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A new route to early-late heterobimetallic μ-alkylidene complexes

✍ Scribed by Charles P. Casey; Fredric R. Askham; Lori M. Petrovich


Book ID
103226896
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
345 KB
Volume
387
Category
Article
ISSN
0022-328X

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Metal insertion into a CH bond as a rout
✍ Charles P. Casey; Yan Wang; Lori M. Petrovich; Todd L. Underiner; Paulette N. Ha 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 849 KB

The reaction of C,H,(CO),Re(CH,)-Li+ -THF (5) with (Ph,P),Pt[(E)-C(CH,)=CHCH,]+CF,SO,-(3E) in an attempt to prepare the heterobimetallic complex C,H,(CO),(CH,)RePt[(E)-C(CH,)=CHCH,](PPh,), (B) led to the formation of the new heterobimetallic p-methylene complex C,H,(CO),Re(@ZHz)Pt(PPh,), (4), which