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A new route to 3-deoxy-d-manno2-octulosonic acid: felkin-anh rule in radical chemistry

✍ Scribed by Bernd Giese; Bertrand Carboni; Thomas Göbel; Ralf Muhn; Frank Wetterich

Book ID: 104215739
Publisher: Elsevier Science
Year: 1992
Tongue: French
Weight: 248 KB
Volume: 33
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)79054-x

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✦ Synopsis

Abstmck Arabinosyl mbalt complex 5 and silylated pyravate 6 give under radical condition the chain elongated sugar derivative 7. a precursor of KIWI (4). The intermediite radical 8 reacts stereoselectively with BKCl3 according to the Felkin-Anh rule.

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