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A new route to 2-substituted perimidines based on nitrile oxide chemistry

✍ Scribed by Iain A.S. Smellie; Andreas Fromm; R. Michael Paton

Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 245 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.04.118

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✦ Synopsis

A new route to perimidines has been developed which involves reaction of a nitrile oxide with 1,8-diaminonaphthalene. Benzonitrile oxide, generated by dehydrochlorination of benzohydroximoyl chloride, and 1,8-diaminonaphthalene afforded 2-phenylperimidine. 2-Pyranosylperimidines were prepared by the same approach from pyranosyl hydroximoyl chlorides.

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