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A New Rotational Study of the Ground Vibrational State of CHD3

โœ Scribed by O.N. Ulenikov; G.A. Onopenko; N.E. Tyabaeva; S. Alanko; M. Koivusaari; R. Anttila

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
423 KB
Volume
186
Category
Article
ISSN
0022-2852

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โœฆ Synopsis

A careful rotational analysis of the ground vibrational state of the CHD 3 molecule is made on the basis of the ground state combination differences method using, as the initial information, transitions from 12 infrared absorption bands: n 3 (A 1 ), n 6 (E), n 5 (E), 2n 3 (A 1 ), 2n 6 (A 1 ), 2n 6 (E), n 3 / n 6 (E), 2n 5 (A 1 ), 2n 5 (E), n 3 / n 5 (E), n 5 / n 6 (A 1 / A 2 ), and n 5 / n 6 (E). More than 2500 ''forbidden'' transitions were used to determine the parameters C, D K , and H K . a 1 0 a 2 (K ร… 3) splittings in the ground vibrational state were found and analyzed.

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