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A new ring transformation of 3-halo-2-azidopyridine 1-oxides. A novel synthesis of 1,2-oxazin-6-ones

✍ Scribed by Rudolph A. Abramovitch; Ichiro Shinkai; Berkeley W. Cue Jr.; Francis A. Ragan Jr.; Jerry L. Atwood


Book ID
112123733
Publisher
Journal of Heterocyclic Chemistry
Year
1976
Tongue
English
Weight
157 KB
Volume
13
Category
Article
ISSN
0022-152X

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A new ring transformation: Synthesis of
✍ Christian Deshayes; Suzanne Gelin πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 358 KB

The nitrosation of some y,&unsaturated B-diketo compounds affords the 3-substituted 4-oxo-5,6-dihydro-1,2,4ff-oxaxines. These compounds are converted to the isomeric 3-oxo-1-pyrroline l-oxides by a facile thermal rearrangement. In connection with our study of y,s-unsaturated 6-ketoesters1'2, we have