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A new ring closure of 1,4-benzodiazepine

✍ Scribed by N. Blažević; F. Kajfež


Book ID
112122283
Publisher
Journal of Heterocyclic Chemistry
Year
1970
Tongue
English
Weight
124 KB
Volume
7
Category
Article
ISSN
0022-152X

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Dianion 2 derived from N-Boc-aminobenzotriazole 1 condenses in a [1.2]fashion with ct, fl-unsaturated aldehydes; subsequent oxidation of the resulting allylic alcohols 7 using manganese(IV) oxide or, less effectively, treatment of the derived acetates 10 with Pd(O), results in direct formation of th