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A new regio- and stereocontrolled access to functionalised silacyclopent-3-enes

✍ Scribed by Yannick Landais; Sheetal S Surange


Book ID
104211548
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
117 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


C-2 functionalised silacyclopent-3-enes were obtained in high yields in only two steps from diallyldiphenylsilane through hydroxy-alkylation of an allyltitanium intermediate followed by ring closure metathesis of the resulting b-hydroxysilane.


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