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A new rearrangement reaction of 2-chloro-1-trimethylsilyl alkoxide. Preparation of β-hydroxyalkyl- or β-ketoalkyltrimethylsilanes

✍ Scribed by Toshio Sato; Toru Abe; Isao Kuwajima


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
221 KB
Volume
19
Category
Article
ISSN
0040-4039

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A new rearrangement reaction of 1-chloro
✍ Isao Kuwajima; Yutaka Fukuda 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 133 KB

We have recently reported that treatment of the C3(-hydroxyaldehyde dlphenylmercaptals (I) with methyl-or n-butyllithlum leads to the formation of the corresponding phenylthlomethyl ketone In high yield.' This reaction Is considered to proceed through an Initial formation of the dlllthlated lntermed