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A new reaction of acetylenes with terminal ternary bonds

✍ Scribed by M. S. Shvartsberg; I. L. Kotlyarevskii; A. N. Kozhevnikova; V. N. Andrievskii


Book ID
112477589
Publisher
Springer
Year
1970
Tongue
English
Weight
334 KB
Volume
19
Category
Article
ISSN
1573-9171

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The reaction of diphenylketene with terminal acetylenes catalyzed by tetrakis-(triphenylphosphine)palladium gave disubstituted acetylenes in high yields. Ketenes are known to undergo a variety of charactaristic reactions and to form complexes with transition metals. ') A currently important area in