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A new reaction of 1,2-di- and 1,2,3-trialkyldiaziridines: Ring expansion under the action of diethyl acetylenedicarboxylate in ionic liquids

✍ Scribed by Yuliya S. Syroeshkina; Vladimir V. Kuznetsov; Vadim V. Kachala; Nina N. Makhova

Publisher: Journal of Heterocyclic Chemistry
Year: 2009
Tongue: English
Weight: 165 KB
Volume: 46
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.204

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✦ Synopsis

Abstract

magnified image New reaction of diaziridine ring expansion resulting in diethyl 1,2,3,6‐tetrahydropyrimidine‐4,5‐dicarboxylate derivatives was discovered under the action of diethyl acetylenedicarboxylate on 1,2‐di‐ and 1,2,3‐trialkyldiaziridines in ionic liquids. J. Heterocyclic Chem., (2009).

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