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A new proton-conductive copper coordination polymer, (HOC3H6)2dtoaCu (dtoa = dithiooxamide)

✍ Scribed by Y. Nagao; R. Ikeda; K. Iijima; T. Kubo; K. Nakasuji; H. Kitagawa

Book ID: 117539622
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 351 KB
Volume: 135-136
Category: Article
ISSN: 0379-6779
DOI: 10.1016/s0379-6779(02)00914-1

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## Abstract A mixed‐valence copper(I,II) coordination polymer [Cu^I^~2~Cu^II^(4,4′‐bpy)~2~(pydc)~2~]·4H~2~O (4,4′‐bpy = 4,4′‐bipyridine and pydc = pyridine‐2,4‐dicarboxylate) featuring the “metal‐complex ligands” [Cu^II^(pydc)~2~]^2−^ was designed and synthesized hydrothermally from Cu(MeCO~2~)~2~,