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A new protocol for the formation of carbamates and thiocarbamates using carbamoyl imidazolium salts

✍ Scribed by Robert A. Batey; Chiaki Yoshina-Ishii; Scott D. Taylor; V. Santhakumar

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 265 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)00302-0

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✦ Synopsis

Carbamoyl imidazolium salts are demonstrated to act as useful carbamoylation reagents, in reactions with alcohols, phenols, thiols and thiophenols to form carbamates and thiocarbamates under relatively mild conditions. The salts are stable and easily prepared from the corresponding amines using CDI.

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