The anionic polymerization of butadiene monomer in cyclohexane at 20Β‘C gave polybutadiene (PB50) with a narrow molecular weight distribution. This polymer was allowed to react with 4-phenyl-1,2,4-triazoline-3,5-dione via the "eneΓ reaction to the extent of 5, 10 and 15%. These functionalized polymer
A new process for producing polyamide from polyester
β Scribed by Seiko Nakano; Tadaya Kato
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 315 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-624X
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β¦ Synopsis
A new process for producing polyamide from polyester and diamine was proposed. An attempt was made to produce polyamide 6T from polyethyleneterephthalate or dimethylterephthalate with hexamethylenediamine in water, o-dichlorobenzene and sulfolane. Characterization of the products by IR, elemental analysis, solution viscosity and GPC were carried out. It became clear that high molecular polyamide 6T could be obtained from polyethyleneterephthalate and hexamethylenediamine in sulfolane. The reaction mechanism was discussed from the viewpoint of the polymer effect and solvent effect.
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## Abstract A new process of producing pure H~2~ in consumption of H~2~O and carbon is presented. It contains three reactions: (1) Steam reacts with FeO at 800Β°C generating pure H~2~ and Fe~3~O~4~/Fe~2~O~3~; (2) Fe~3~O~4~/Fe~2~O~3~ are reduced to FeO by CO at same temperature while CO changes to CO