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A new process for preparing dialdehyde by catalytic oxidation of cyclic olefins with aqueous hydrogen peroxide

✍ Scribed by Yu Hong-Kun; Pang Zhen; Huang Zu-En; Cai Rui-Fang

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
239 KB
Volume
18
Category
Article
ISSN
0256-7660

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## Abstract It was found that __tert__‐BuNH~2~ is an efficient catalyst for epoxidation of __Ξ±__,__Ξ²__‐unsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%–93%) were obtained within 24 h period.