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A new procedure for the synthesis of C-glycosides of nojirimycin

✍ Scribed by Cipolla, Laura; La Ferla, Barbara; Peri, Francesco; Nicotra, Francesco

Book ID
120468440
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
151 KB
Volume
14
Category
Article
ISSN
1359-7345

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## Abstract Methyl 2,3,4,6‐tetra‐__O__‐acetyl‐__N__‐(benzyloxycarbonyl)nojirimycin (3) can be readily transformed into the corresponding azaglycal 6 or fluoride 7, which are versatile glycosyl/piperidinosyl donors. Reaction of 7 with allyltrimethylsilane, propinyltrimethylsilane, trimethylsilyl cya