A new polyphenylene derivative bearing two stable radicals
โ Scribed by Ruifeng Zhang; Haipeng Zheng; Jiacong Shen
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 227 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
โฆ Synopsis
Hydroxylization of poly(N,N-dimethylaniline) (PDMA) by using H202 in base medium gives rise to a new polyphenylene derivative containing a high concentration of stable phenoxy radicals in the solid state. In solution, hydroxylated PDMA can have two forms of stable radicals, phenoxy radical and radical cation, and these two forms can be converted reversibly into each other by adjusting the pH value of the solution.
๐ SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
## Abstract **Summary:** The synthesis of the new __ฮฑ__โhydrogen bearing nitroxide, 2,2,5โtrimethylโ4โ(isopropyl)โ3โazahexaneโ3โoxyl (BIPNO) (**4**), and its corresponding alkoxyamine, __N__โ__tert__โbutylโ__N__โ(1โisopropylโ2โmethylโpropyl)โ__O__โ(1โphenylโethyl)โhydroxylamine (PhEtโBIPNO) (**7**)
## Abstract For Abstract see ChemInform Abstract in Full Text.