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A new polyphenylene derivative bearing two stable radicals

โœ Scribed by Ruifeng Zhang; Haipeng Zheng; Jiacong Shen


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
227 KB
Volume
18
Category
Article
ISSN
1022-1336

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โœฆ Synopsis


Hydroxylization of poly(N,N-dimethylaniline) (PDMA) by using H202 in base medium gives rise to a new polyphenylene derivative containing a high concentration of stable phenoxy radicals in the solid state. In solution, hydroxylated PDMA can have two forms of stable radicals, phenoxy radical and radical cation, and these two forms can be converted reversibly into each other by adjusting the pH value of the solution.


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