A new polymorph of 2,2,4,4,6,6-hexaisothiocyanatocyclotriphosphazene
✍ Scribed by Kessenich, Elmar ;Schulz, Axel ;Polborn, Kurt
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 253 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(N±C) = 0.009 A Ê R factor = 0.055 wR factor = 0.131 Data-to-parameter ratio = 13.4
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📜 SIMILAR VOLUMES
The condensation reactions of N 2 O x (xZ2, 3) donor type bifunctional aminopodands 1-4 with hexachlorocyclotriphosphazatriene, N 3 P 3 Cl 6 , have been investigated and the partly substituted 5-8 novel spiro-cyclic phosphaza (PNP) lariat ethers, having various different ring sizes between 11 and 14
The title compound, C 22 H 15 Cl 4 N 4 O 2 P 3 , is a spiro phosphazene derivative with two bulky naphthalene rings. The phosphazene and the two six-membered N/O rings are not planar. The aliphatic C atom (in ArCH-OAr) and the N atom (in ArCH 2 -N), which has a pyramidal geometry, are capable of rep