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A New Phenomenon in Phase-transfer Catalysis (PTC): Topoinduced Stereoselectivity in the Phase-transfer Phenolysis of Cyclophosphazenes

✍ Scribed by Nina G. Razumova; Aleksandr E. Shumeiko; Anatolii A. Afon’kin; Anatolii F. Popov

Book ID
111729582
Publisher
Royal Society of Chemistry
Year
1994
Tongue
English
Weight
277 KB
Volume
4
Category
Article
ISSN
0959-9436

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The kinetics of phase-transfer catalyzed etheri®cation of sodium phenoxide with ethyl 2-bromoisobutyrate to produce ethyl 2-phenoxyisobutyrate in a solid±liquid system has been investigated. Being catalyzed by the quaternary `onium salts, the reaction was carried out in a stirred batch reactor to ex