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A new pathway for the synthesis of 1,3-dioxa-6-aza-2-germacyclooctanes: molecular structure of 2,2-di(2-thienyl)-6-methyl-1,3-dioxa-6-aza-2-germacyclooctane

โœ Scribed by Edmunds Lukevics; Sergey Belyakov; Olga Pudova


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
538 KB
Volume
523
Category
Article
ISSN
0022-328X

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โœ Andrea Trabocchi; Gloria Menchi; Massimo Rolla; Fabrizio Machetti; Ilaria Bucell ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

New methodology for the synthesis of enantiopure 3-aza-6,8-dioxa-bicyclo[3.2.1]octane-carboxylic acids belonging to 7-endo-BTAa sub-class of g/d amino acids is described. The novelty is the use of 2,3-O-isopropylidene-erythrose instead of meso-tartaric acid derivative, thus allowing us to perform an