A New Paramagnetic Pd(dmit)2 Salt: Tris(2,2′-Bipyridine)Nickel(II) Bis(1,3-Dithiole-2-Thione-4,5-Dithiolato)Palladate(II) Mono-Acetonitrile; [Ni(bpy)3][Pd(dmit)2]·CH3CN
✍ Scribed by Martijn J.J. Mulder; Christophe Faulmann; Jaap G. Haasnoot; Jan Reedijk
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 392 KB
- Volume
- 168
- Category
- Article
- ISSN
- 0022-4596
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✦ Synopsis
Combination of the [Ni(bpy) 3 ] 2+ cation complex and the [Pd(dmit) 2 ] À anion (dmit=C 3 S 5 2À =1,3-dithiole-2thione-4,5dithiolate) has resulted in the paramagnetic [Ni(bpy) 3 ][Pd (dmit) 2 ] . CH 3 CN compound, a suitable precursor for a molecular magnetic conductor. Its crystal structure consists of a Pd(dmit) 2 anion arrangement that is quite different from segregated stack layers often found for M(dmit) 2 Àbased compounds. The reduction of the [Pd(dmit) 2 ] -to the 2À charged anion in the title compound most probably is the result of a charge disproportionation between Pd(dmit) 2 anions. # 2002 Elsevier Science (USA)