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A new nickel(II) complex with a [14]N4 macrocyclic ligand

✍ Scribed by Yu, Ming ;Yang, Guang-Ming

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
303 KB
Volume
61
Category
Article
ISSN
1600-5368

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πŸ“œ SIMILAR VOLUMES

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Three N,S2 macrocycles (3,10,12) carrying an amino group as a pendant arm have been synthesized and their complexation properties towards Ni2+ and Cu2+ studied. The crystal structures of the Cu2+ complexes with lO-methyl-l,4-dithia-7,lO-diazacyclododecane-7-ethanamine (3) and 1 1-methyl-1,4-dithia-8

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ESR and absorption spectra were measured for the square planar cobalt(II), nickel(II) and copper complexes with some I4, 15 and 16membered N4macrocyclic ligands, such as (14-a), H(14-b), H,(14c), HJIS-c) and H,(16-c) (for the abbreviations, see Fig. 2 in the text). On the basis of the ESR spectra of