A new modification of the method of investigation of vibration-rotation interactions in molecules
✍ Scribed by Yu.S. Makushkin; Vl.G. Tyuterev
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 199 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0375-9601
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📜 SIMILAR VOLUMES
The potential model of G. Thompson et al. [J. Mol. Spectrosc. 124, 130-138 (1987)] for an analysis of the vibrational-rotational and the rotational spectra of diatomic molecules is modified by an algebraic WKB treatment of the Schro ¨dinger equation given by Watson's effective Hamiltonian. A compact
The commutator perturbation method, an algebraic version of the Van Vleck-Primas perturbation method, expressed in terms of ladder operators, has been applied to solving the eigenvalue problem of the Hamiltonian describing the vibrational-rotational motion of a diatomic molecule. The physical model
The problem of the determination of the vibration-rotation eigenvalue in diatomic molecules is considered. An eigenvalue equation totally independent from the eigenfunction is written for any potential, analytical or numerical. This equation uses uniquely the vibration-rotation canonical functions;