A new model describing the kinetics of micelle formation from chemical relaxation studies

✍ Scribed by P.J. Sams; E. Wyn-Jones; J. Rassing

• Publisher: Elsevier Science
• Year: 1972
• Tongue: English
• Weight: 520 KB
• Volume: 13
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(72)85049-8

✦ Synopsis

Cherricat rel&&on stud& k iotiic surface &tiw, agents in aqueous solutions have: been carried outu% kg ultrasonic fl-61; t~~~rature f7-93 and pressure [IO] jump techniques. In af$ these experimknts a single relaxation has been observed at surfactant con-.centrations cIose to the' c.m.c. This relaxation, ivhose re&procaI r&xation timk increases linearly with in-c&sing ~oricentration of surfactant; has be& attri-' buted to, the, perturbation of equebria involving rni* cd.hx The detailed mechanisms proposed far these,, equilibria we, however>'very ~~fferent_..Yas~a~a et al.: