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A new method for the synthesis of the marine alkaloid fascaplysin

โœ Scribed by Maxim E. Zhidkov; Olga V. Baranova; Natalya S. Kravchenko; Sergey V. Dubovitskii

Book ID
104098394
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
179 KB
Volume
51
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Total synthesis of the marine sponge pig
Total synthesis of the marine sponge pigment fascaplysin
โœ Benjamin Pelcman; Gordon W Gribble ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 248 KB

Fascaplysin (I), an antimicrobial and cytotoxic red pigment from the marine sponge Fascaplysinopsis sp., has been synthesized in seven steps from indole (65% yield). The pivotal intermediate in the synthesis is diindole 3 which is induced to undergo acid-catalyzed cyclization and dehydrogenation to