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A new method for the synthesis of O-glycosides from S-glycosides

โœ Scribed by Pozsgay, Vince; Jennings, Harold J.

Book ID
126136216
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
396 KB
Volume
52
Category
Article
ISSN
0022-3263

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Almond โค-glucosidase was used to catalyze the synthesis of alkyl โค-Dglucopyranosides 1b-3b starting from either D-glucose (4) or phenyl-โค-Dglucopyranoside (5) and the racemic alcohols 1a-3a. The enzymic reactions were provided in different acetonitrile/water mixtures [9:1 (v/v) for the reverse hydro