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A new method for the synthesis of fluorinated vinyl sulfides and ketene dithioacetals

โœ Scribed by A. N. Kovregin; A. Yu. Sizov; A. F. Ermolov


Book ID
110299972
Publisher
Springer
Year
2001
Tongue
English
Weight
239 KB
Volume
50
Category
Article
ISSN
1573-9171

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Fluorinated ketene dithioacetals. Part I
โœ Vadim M Timoshenko; Jean-Philippe Bouillon; Yuriy G Shermolovich; Charles Portel ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 92 KB

4-Fluoro-5-perfluoroalkyl-3H-1,2-dithiole-3-thiones were prepared by heating the corresponding ketene dithioacetals with magnesium bromide and elemental sulfur. They reacted as dienophiles and 1,3-dipoles in cycloaddition reactions to give new fluorinated organosulfur compounds.