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A New Method for the Synthesis of Dithiocarbamates by CuI-Catalyzed Coupling Reaction.

✍ Scribed by Yunyun Liu; Weiliang Bao


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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This article reports a detailed reinvestigation of the reaction of bis(dialkyldithiocarbamato)zinc(II) (ZDAC) with amines. The reaction of primary amines with bis(dimethyldithiocarbamato)zinc(II) (ZDMC) results in the formation of a 1,1,3-trisubstituted thiourea, a 1,3-disubstituted thiourea, dimeth