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A new method for the microstructure determination of polybutadiene with cis-1,4, trans-1,4, and vinyl-1,2 units by carbon-13 NMR

✍ Scribed by Van der Velden, Geert; Didden, Cees; Veermans, Ton; Beulen, Jo


Book ID
120290043
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
559 KB
Volume
20
Category
Article
ISSN
0024-9297

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Carbon-13 NMR spectra of 1,3-dioxolanes.
✍ Antonio Espinosa; Miguel A. Gallo; JoaquΓ­n Campos; Antonio Entrena; EncarnaciΓ³n πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 465 KB

The uC NMR spectra of 24 1,3-dioxoIane derivatives are reported in an attempt to propose parameters for the C-2, C-4 and C-5 shifts from the %Me and 4-Me substituents, based on the ring stereochemistry. These parameters are obtained from simultaneous equations, and clearly agree with those Calculate