𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new method for the generation and capture of iminylradicals

✍ Scribed by Jean Boivin; Anne-Marie Schiano; Samir Z. Zard; Haiwen Zhang

Book ID
104261503
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
243 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

hninyl radicals can be generated from ketoxime esu~ and capueed by an internal olefin; the sequence may be terminated in a variety of ways depending on the nature of the ensuing carbon radical and the added external trap.

πŸ“œ SIMILAR VOLUMES

A new method for the generation of subst
A new method for the generation of substituted homotrimethylenemethane diradicals
✍ Daniel J. Pasto; David E. Alonso πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 254 KB

+ 21 Cycloaddition; Diical Ring-Closum Absrract The elimination of nitrogen from the l.ldiaxine 11 pmduces the bomotrimethylenemethane diradicall2 which undergoes ring closum to form the substituted methylenecyclobutanes 13 and 14. No cleavage of the diradical intermediate to produce 1,ldimethylalle

Thermolysis of Imidates: A New Method fo
Thermolysis of Imidates: A New Method for the Generation of Carbonyl Ylides
✍ Vsevolodβ€…V. Nikolaev; Anthony Linden; Heinz Heimgartner πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 German βš– 287 KB

## Abstract Thermolysis of dimethyl 2‐[(3‐oxo‐3__H__‐isoindol‐1‐yl)oxy]malonate (**8**) promotes a [1,4]‐H shift in the imidic ο£ΏNο£ΎCο£ΏOο£ΏCHο£Ώ fragment of the starting molecule, which leads to a reactive carbonyl ylide. This carbonyl ylide can be trapped by the Cο£ΎN bond of imidates and imines, as well a