𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new method for the bishomologation of carbonyl compounds to α,β-unsaturated aldehydes via the [3,3]sigmatropic rearrangement of allylic thionocarbamates

✍ Scribed by Takeshi Nakai; Tetsuya Mimura; Akira Ari-Izumi

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
220 KB
Volume
18
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The aldol condensation continues to play a fundamental role in organic synthesis and many methods have recently been developed for directing the aldol condensation of nonidentical carbonyl partners.2) A novel approach to the directed aldol condensation involves a two-carbon

📜 SIMILAR VOLUMES

General synthetic routes to α,β-unsatura
General synthetic routes to α,β-unsaturated carboxylic esters and ketones via the [3,3]sigmatropic rearrangement of allylic thioncarbamates. Stereospecific syntheses of two ant mandibular gland secretions
✍ Takeshi Nakai; Tetsuya Mimura; Takashi Kurokawa 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 235 KB

00~~~0~g/~8/~01-28g~2.00/0 @ Eergamca F'rmm Ltd.1978. Frinted in oreat Ibritdn. ## GENERAL SYNTHETIC ROUTES TO a,&UNSATURATED CARBOXYLIC ESTERS AND KETONES REARRANGEMENT OF ALLYLIC THIONCARBAMATES.