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A new method for luminescent porous silicon formation: reaction-induced vapor-phase stain etch

✍ Scribed by de Vasconcelos, Elder A. ;da Silva, E. F. ;dos Santos, B. E. C. A. ;de Azevedo, W. M. ;Freire, J. A. K.


Book ID
105363151
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
134 KB
Volume
202
Category
Article
ISSN
0031-8965

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✦ Synopsis


Abstract

We report a new method to form reproducible luminescent porous silicon layers in p‐type and n‐type substrates of low and high resisivity, with minimum apparatus and maximum simplicity. No equipment, formation of electrical contacts, illumination or addition of surfactants is needed. The porous silicon layer is formed by exposing the Si surface to the vapor generated by a dissolution reaction of a metal or Si in a HF/HNO~3~ mixture. The PL spectra of the layers have peaks located from 1.85 eV to 2.1 eV. The current–voltage characteristics of Al/PS/p‐Si/Al devices formed on these layers are rectifying and follow an exponential dependence at low forward bias and a power law at high forward bias. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)