Synthesis and X-ray Crystal Structure of
โ
Berkessel, Albrecht ;Bolte, Michael ;Neumann, Thomas ;Seidel, Lutz
๐
Article
๐
1996
๐
Wiley (John Wiley & Sons)
๐
English
โ 818 KB
The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th