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A new mechanism of the photochemical oxidation of tryptophan sensitised with the uranyl ion

✍ Scribed by Sergey S. Ostakhov; Valerii P. Kazakov; Irina O. Osina

Book ID
108209721
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
255 KB
Volume
19
Category
Article
ISSN
0959-9436

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The Photochemical Behavior of the Uranyl
The Photochemical Behavior of the Uranyl Ion (UO): a Dimer Perspective and Outlook
✍ Christiane GΓΆrller-Walrand; Kelly Servaes πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 German βš– 520 KB

## Abstract The complex formation of uranyl (UO$\rm{ {\_{2}^{2+}}}$) with oxalic acid (HOOCο£ΏCOOH) in acetone is studied by UV/VIS, absorption, luminescence, and excitation spectroscopy. Based on solid‐state crystallographic data, we propose a dimer structure with __D__~2h~ symmetry for the complex