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A new mechanism for providing stable molecular products in high energy reactions

✍ Scribed by Muriel Sizun; Gérard Parlant; Eric A. Gislason


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
424 KB
Volume
139
Category
Article
ISSN
0009-2614

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✦ Synopsis


A new mechanism for stabilizing product molecules in high-energy chemical reactions is described. It was discovered in quasiclassical trajectory studies of the reactions of Cl-+H2. It should apply to a wide range of reactions, and it may be the primary source of product molecules with internal energies well below the dissociation limit. It was quite different from the sequential impulse model, which can also give stable products.