Synthesis and Structure of [Sn4Se11]6โ,
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Anja Loose; William S. Sheldrick
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Article
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1999
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John Wiley and Sons
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German
โ 205 KB
๐ 2 views
Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115ยฑ130 ยฐC affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ยดx H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6ยฑ anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4ยฑ species. Similar re