A new linewidth variation in the ESR spectrum of the hydroxy methyl radical: Direct observation during continuous radiolysis with 3 MeV electrons

✍ Scribed by F.P. Sargent; E.M. Grady

• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 289 KB
• Volume: 38
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(76)80272-2

✦ Synopsis

Ilie hydrosy methyl radical, i:H,CIH, ws directly obscrvctl by ESK during continuous radiolysis of liquid rnctllilnol with 3 hlcV clcctrons. The ESK spatrum showed a novel iincwidth variation effect. Various mechanisms wcrc considered to account for tlli< but low amplitude torsiomll motion about the C--O bond is shown to be the moqt likely.