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A new irregular diterpene skeleton from Anisotome flexuosa

✍ Scribed by John W. van Klink; Anna J. Barlow; Nigel B. Perry; Rex T. Weavers

Book ID
104260576
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
200 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

A novel class of irregular diterpene has been discovered in the New Zealand subalpine plant Anisotome flexuosa Dawson (Apiaceae/Umbelliferae). The structure and relative stereochemistry ofanisotomenoic acid 4 (3,3a,4,4tetramethy

acid) was determined by NMR correlation experiments conducted on 4 and a primary alcohol derivative 5 (3,3a,4,4-tetramethyl-3-(4-methyl-3-pentenyl)-2,3,3a,4,5,6-hexahydro-1H-2-indenyl) methanol). Alcohol 5 was subsequently confirmed as a natural product.

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