A new initiator cholesteryl chloroformate for cupper-based atom transfer radical polymerization of methyl methacrylate
✍ Scribed by Jian Cao; Juan Chu; Ke-Da Zhang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 320 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0256-7660
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## Abstract This investigation reports the preparation of poly(methyl methacrylate)s bearing amino adamantyl functionality as the end‐group via atom transfer radical polymerization (ATRP) using amino‐adamantyl isobutyryl bromide (Am‐AdiBr) as initiator. The rate of polymerization was slow compared
## Abstract Well‐defined poly(vinyl acetate‐__b__‐methyl methacrylate) block copolymers were successfully synthesized by the atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) in __p__‐xylene with CuBr as a catalyst, 2,2′‐bipyridine as a ligand, and trichloromethyl‐end‐grouped
## Abstract Summary: The homogeneous bulk reverse ATRP using AIBN/Cu(SC(S)N(C~4~H~9~)~2~)~2~/bpy as the initiating system has been successfully carried out for methyl methacrylate. Well‐controlled polymerizations with low polydispersities ($\overline M \_{\rm w} /\overline M \_{\rm n}$ = 1.10–1.30)