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A new hyperbranched polymer with polar chromophores for nonlinear optics

โœ Scribed by Yadong Zhang; Tatsuo Wada; Hiroyuki Sasabe

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
424 KB
Volume
38
Category
Article
ISSN
0032-3861

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โœฆ Synopsis

A new three-dimensional hyperbranched polymer with 4-(2-cyano-2-methoxy-carbonylvinyl)aniline as a second-order nonlinear optical chromophore has been synthesized starting from 4-formyl-N,N-di(2hydroxyethyl)aniline and cyanoacetic acid by a one-pot Knoevenagel polycondensation using 4-(dimethylamino)pyridine as a base. This hyperbranched polymer with a good solubility in polar organic solvents, such as N,N-dimethylformamide and methyl sulfoxide, was characterized by 'H n.m.r., i.r. and u.v.-vis spectroscopies. Differential scanning calorimeter analysis showed that this polymer exhibited a glass transition temperature at 86ยฐC. The second-harmonic generation signal has been observed from the poled films of this hyperbranched polymer.

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