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A New Hydroxydiphosphine as a Ligand for Rh(I)-Catalyzed Enantioselective Hydrogenation.

โœ Scribed by Igor V. Komarov; Axel Monsees; Renat Kadyrov; Christine Fischer; Ute Schmidt; Armin Boerner


Publisher
John Wiley and Sons
Year
2003
Weight
192 KB
Volume
34
Category
Article
ISSN
0931-7597

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Modular P-Chirogenic Aminophosphane-Phos
โœ Christophe Darcel; Dominique Moulin; Jean-Christophe Henry; Michaรซl Lagrelette; ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 258 KB

## Abstract An original series of Pโ€chirogenic aminophosphaneโ€phosphinite (AMPP) ligands has been synthesized from (+)โ€ or(โ€“)โ€ephedrine in 23 to 61โ€‰% overall yields by a versatile threeโ€step methodology. The AMPP ligands, bearing either one or two Pโ€chirogenic centers, were used in the form of rhod