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A new hydroxy-lactonization of olefinic acids

✍ Scribed by James B. Hendrickson; Vishwakarma Singh


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
195 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


Bicyclic olefin acids affcrc. m-hydroxy-lactones with aqueous calcium hypochlorite. Monocyclic ana acyclic olefin acids yield mainly the corresponding (opened) dihydroxy acids.

In the course of some synthe-Lit work using bicyclic lactones we required a quick preparation of trans-hydroxy-lactones,especially 2 from the double adduct,ll. m-Chloroperbenzoic acid yielded only complex products and


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Enantioselective synthesis of the hydrox
✍ Ray McCague; Horacio F. Olivo; Stanley M. Roberts πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 154 KB

was .msolved. with Pseudomqnas jluoye~pase and one of the enanttomers was convetted mto a hey mtermedtate in the synthests of mevmr .