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A New Hydrindanone Synthesis

✍ Scribed by Massimo Curini; Francesco Epifano; Maria Carla Marcotullio; Ornelio Rosati; Yousheng Guan; Ernest Wenkert

Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
77 KB
Volume
83
Category
Article
ISSN
0018-019X

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✦ Synopsis

The Kanematsu transformation was employed for the preparation of tetrahydroisobenzofuran-4-carboxylic acid (12), a-methylation, subsequent conversion into the diazoethanone 14, and, finally, treatment with dirhodium tetraacetate of which furnished the hydrindanone 1 of the steroid C-D ring structure.

Scheme 1

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