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A new hybrid Keggin-type molybdophosphate: (H2phen)[Cu(phen)2][PMo12O40]

✍ Scribed by Li, Ming-Xue ;Yu, Li ;Bi, Dong-Qin ;Wang, Jing-Ping


Book ID
104487901
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
221 KB
Volume
62
Category
Article
ISSN
1600-5368

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✍ Yue-Qing Zheng; Jian-Li Lin; Jie Sun 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 198 KB 👁 1 views

The reaction of CuCl 2 ´2 H 2 O, 1,10-phenanthroline (phen), suberic acid and Na 2 CO 3 in a CH 3 CN±H 2 O solution yielded blue needle-like crystals of [Cu 2 (phen) 2 (C 8 H 12 O 4 ) 2 ] 3 H 2 O. The crystal structure (monoclinic, P2 1 /n, a = 10.756(2) A Ê , b = 9.790(2) A Ê , c = 18.593(4) A Ê ,