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A new host 2,3,6,7,10,11-hexahydroxy triphenylene which forms chiral inclusion crystalline lattice: X-ray structural study of the chiral crystalline lattice

✍ Scribed by Fumio Toda; Koichi Tanaka; Takeshi Matsumoto; Tadashi Nakai; Ikuko Miyahara; Ken Hirotsu

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 138 KB
Volume: 13
Category: Article
ISSN: 0894-3230
DOI: 10.1002/(sici)1099-1395(200001)13:1<39::aid-poc203>3.0.co;2-8

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✦ Synopsis

The title compound was found to form an inclusion complex crystal with various kinds of guests. It was also found that crystalline lattice of some inclusion complex is chiral. By an enantioselective inclusion complexation in the chiral lattice, the racemic guest was resolved. The chiral crystalline lattice was studied by X-ray analysis. Solidstate synthesis of the title host compound is also described.