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A new, highly stereoselective reducing agent, potassium 9-(2,3-dimethyl-2-butoxy)-9-boratabicyclo[3.3.1]nonane

โœ Scribed by Brown, Herbert C.; Cha, Jin Soon; Nazer, Behrooz


Book ID
126235464
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
267 KB
Volume
49
Category
Article
ISSN
0022-3263

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Stereoselective synthesis of endo-1,3 di
โœ Julian Adams; Richard Frenette ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 135 KB

The title compound was synthesized using a novel approach to form a C3.2.11 oxabicyclic ring system. This was achieved through an intramolecular C-H insertion of a carbenoid intermediate. ## Endo -1,3-dimethyl-2,9-dioxabicycloC3.3.11 nonane 1. isolated from Norway spruce, was found to be a host s