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A new, highly efficient method for the conversion of alcohols to thiolesters and thiols

โœ Scribed by R.P. Volante

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
176 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Various alcohols were converted to their corresponding thiolacetates by treatment with triphenylphosphine and diisopropyl azodicarboxylate in the presence of thiolacetlc acid. The overall conversion was both highly efficient (89-99X yields) and stereoselective (99.5% inversion).

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