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A New Heterogenization Technique for Single-Site Polymerization Catalysts

โœ Scribed by Michael Bartke; Marita Oksman; Marja Mustonen; Peter Denifl


Book ID
111700997
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
266 KB
Volume
290
Category
Article
ISSN
1438-7492

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Redox Control within Single-Site Polymer
โœ Gregson, Charlotte K. A.; Gibson, Vernon C.; Long, Nicholas J.; Marshall, Edward ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 95 KB

The activity of a single-site titanium-based lactide polymerization initiator supported by a ferrocenyl-derivatized salen ligand is shown to be modulated by a chemical redox switch; a substantially higher rate of propagation is found for the neutral catalyst compared to its oxidized dicationic ferro