## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A new group of liquid crystals based on perfluoroalkylated carbohydrates
β Scribed by Martin Hein; Ralf Miethchen
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 178 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The mesogenic fluoroalky113-D-glucopyranosides 5a-d (smectic A) were generated via a dithionite initiated addition of the homologous 1-iodo-perfluoroalkanes la-d to allyl 2,3.4,6-tetra-O-ace%l-J3-D-glucopyranoside (2) forming 3a-d followed by hydrodeiodination to 4a-d and deaceD'lation.
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Several benzodiazepines were enantioresolved on a new carbohydrate chiral stationary phase based on maltooligosaccharides. The role of organic modifier, ionic strength, pH and temperature are examined and the results are discussed. In general, selectivity and retention were found to decrease with in