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A New Generation of 6,6′-Disubstituted 2,2′-Bipyridines: Towards Novel Oligo(bipyridine) Building Blocks for Potential Applications in Materials Science and Supramolecular Chemistry

✍ Scribed by Ulrich S. Schubert; Jörg L. Kersten; Alexander E. Pemp; Claus D. Eisenbach; George R. Newkome


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
320 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis


The 6,6Ј-disubstituted 2,2Ј-bipyridines and oligo (bipyridines) functionality and reasonable solubility behavior. These molecules permit the synthesis of a wide range of are often used as ligands in supramolecular chemistry; however, their range of application has been limited due to functionalized oligo(bipyridines) with new potential applications in supramolecular chemistry and materials the lack of unsymmetrically functionalized compounds and their poor solubility. We describe herein a new generation of science. As initial examples, we present the synthesis of mono-and bis-functionalized bis-and tris-2,2Ј-biypridines. specially designed unsymmetrical bipyridine building blocks possessing different protecting groups for the hydroxy