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A new general approach for the stereocontrolled synthesis of functionalised γ- and δ-lactams

✍ Scribed by Daly, Mark; Gill, Kathryn; Sime, Mairi; Simpson, Graham L.; Sutherland, Andrew

Book ID
120014826
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
401 KB
Volume
9
Category
Article
ISSN
1477-0520

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Substituent directed oxidative cyclization with cetyltrimethylammonium permanganate: A general approach to the synthesis of γ- and δ-lactones
✍ Rajendra Rathore; Padma S. Vankar; S. Chandrasekaran 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 224 KB

Treatment of primary, secondary or tertiary 7-and b-hydroxyolefins with cetyltrimethylammonium permanganate gives good yields of 7-and 6-lactones by oxidative cyclization, with loss of one carbon.